Rhodes, a three-time all-CAA Football selection, recently finished his senior season with 341 career tackles, ranking fifth on William & Mary's all-time list.
Norfolk State outside linebacker Deon King and Idaho State defensive tackle Tyler Kuder also accepted invitations to the all-star game for seniors. Former NFL coaches Mike Holmgren and Mike Martz will serve as this year's head coaches.
The three additions push the number of announced FCS players in the game to 13, including:
Florida A&M linebacker Akil Blount
Western Carolina defensive tackle Helva Matungulu
Campbell defensive tackle Greg Milhouse
Northwestern State quarterback Stephen Rivers
Incarnate Word linebacker Myke Tavarres
Hampton offensive lineman Torian White